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Theoretical study of the effect of alpha-substituents on the 29Si hfs constant in silyl...
- Source :
-
Journal of the American Chemical Society . 12/15/93, Vol. 115 Issue 25, p11926. 4p. 2 Diagrams, 3 Charts, 4 Graphs. - Publication Year :
- 1993
-
Abstract
- Presents a theoretical study of the effect of alpha-substituents on the silicon (Si) hyperfine splitting (hfs) constant in silyl radicals. Arrangement of atoms; Magnitude and trends of Si hfs constant from ESR spectra; Relation between the structure at the radical site and Si hybridization in the singly occupied molecular orbital.
- Subjects :
- *HYPERFINE interactions
*RADICALS (Chemistry)
*REACTIVITY (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 115
- Issue :
- 25
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 9412160034
- Full Text :
- https://doi.org/10.1021/ja00078a034