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Rate-determining carbonyl hydration in the intramolecular hydrolysis of phenacyl phosphonate...
- Source :
-
Journal of the American Chemical Society . 11/17/93, Vol. 115 Issue 23, p10471. 6p. 3 Diagrams, 4 Charts, 2 Graphs. - Publication Year :
- 1993
-
Abstract
- Studies the isotopic probes and activation parameters in the rate-determining carbonyl hydration in the intramolecular hydrolysis of phenacyl phosphonate esters. Decomposition of 4-nitrophenyl 4-substituted-phenacyl methylphosphonate esters in aqueous buffers compared to analogs with alkoxy substituents without a beta-carbonyl group; Activation parameters.
- Subjects :
- *PHOSPHONATES
*ESTERS
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 115
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 9412270001
- Full Text :
- https://doi.org/10.1021/ja00076a001