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Palladium-Catalyzed Double Alkylation of 3-Aryl-2-fluoroallyl Esters with Malonate Nucleophiles through the Carbon–Fluorine Bond Cleavage.
- Source :
-
Organic Letters . Feb2014, Vol. 16 Issue 3, p700-703. 4p. - Publication Year :
- 2014
-
Abstract
- Thealkylation of (Z)-3-aryl-2-fluoroallyl acetatewith the malonate anion by the [Pd(C3H5)(cod)]BF4/2,2′-bpy catalyst proceeds through the carbon–fluorinebond cleavage, and 2 equiv of the malonate nucleophile was introducedto the allyl substrate. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 16
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 94429958
- Full Text :
- https://doi.org/10.1021/ol500121z