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Hydrogen-bonded chains in three cis-dichloridoplatinum(II) complexes bearing piperidine and amine ligands.
- Source :
-
Acta Crystallographica Section C: Structural Chemistry . Mar2014, Vol. 70 Issue 3, p297-301. 5p. - Publication Year :
- 2014
-
Abstract
- The crystal structures of cis-dichlorido(ethylamine-κ N)(piperidine-κ N)platinum(II), [PtCl2(C2H7N)(C5H11N)], (I), cis-dichlorido(3-methoxyaniline-κ N)(piperidine-κ N)platinum(II), [PtCl2(C5H11N)(C7H9NO)], (II), and cis-dichlorido(piperidine-κ N)(quinoline-κ N)platinum(II), [PtCl2(C5H11N)(C9H7N)], (III), have been determined at 100 K in order to verify the influence of the nonpiperidine ligand on the geometry and crystal packing. The crystal packing is characterized by N-H...Cl hydrogen bonding, resulting in the formation of chains of molecules connected in a head-to-tail fashion. Hydrogen-bonding interactions play a major role in the packing of (I), where the chains further aggregate into planes, but less so in the case of (II) and (III), where π-π stacking interactions are of greater importance. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 20532296
- Volume :
- 70
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica Section C: Structural Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 94758875
- Full Text :
- https://doi.org/10.1107/S2053229614003386