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Gold Supportedon Iron Oxide Nanodisk as EfficientCatalyst for The Removal of Toluene.
- Source :
-
Industrial & Engineering Chemistry Research . Mar2014, Vol. 53 Issue 9, p3486-3494. 9p. - Publication Year :
- 2014
-
Abstract
- Inthe present study, nanodisk-like Fe2O3was firstprepared using the hydrothermal method, and then its supportedgold catalysts (xAu/Fe2O3nanodisk, x= 0.71â6.55 wt %) were fabricated using the polyvinylalcohol-protected reduction method. Under the reaction conditionsof toluene concentration = 1000 ppm, toluene/O2molar ratio= 1/400, and space velocity = 20â000 mL/(g h), 6.55Au/Fe2O3nanodisk performed the best (T50%= 200 °C and T90%= 260 °C). The apparent activation energies (46â50 kJ/mol)obtained over the xAu/Fe2O3nanodisk were smaller than that (65 kJ/mol) obtained over the Fe2O3nanodisk for toluene oxidation. We concludethat the high oxygen adspecies concentration, good low-temperaturereducibility, and strong interaction between Au nanoparticles andthe Fe2O3nanodisk are responsible for the highcatalytic performance of the 6.55Au/Fe2O3nanodisk. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 08885885
- Volume :
- 53
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Industrial & Engineering Chemistry Research
- Publication Type :
- Academic Journal
- Accession number :
- 94778237
- Full Text :
- https://doi.org/10.1021/ie5000505