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Gold Supportedon Iron Oxide Nanodisk as EfficientCatalyst for The Removal of Toluene.

Authors :
Han, Wen
Deng, Jiguang
Xie, Shaohua
Yang, Huanggen
Dai, Hongxing
Au, Chak Tong
Source :
Industrial & Engineering Chemistry Research. Mar2014, Vol. 53 Issue 9, p3486-3494. 9p.
Publication Year :
2014

Abstract

Inthe present study, nanodisk-like Fe2O3was firstprepared using the hydrothermal method, and then its supportedgold catalysts (xAu/Fe2O3nanodisk, x= 0.71–6.55 wt %) were fabricated using the polyvinylalcohol-protected reduction method. Under the reaction conditionsof toluene concentration = 1000 ppm, toluene/O2molar ratio= 1/400, and space velocity = 20 000 mL/(g h), 6.55Au/Fe2O3nanodisk performed the best (T50%= 200 °C and T90%= 260 °C). The apparent activation energies (46–50 kJ/mol)obtained over the xAu/Fe2O3nanodisk were smaller than that (65 kJ/mol) obtained over the Fe2O3nanodisk for toluene oxidation. We concludethat the high oxygen adspecies concentration, good low-temperaturereducibility, and strong interaction between Au nanoparticles andthe Fe2O3nanodisk are responsible for the highcatalytic performance of the 6.55Au/Fe2O3nanodisk. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
08885885
Volume :
53
Issue :
9
Database :
Academic Search Index
Journal :
Industrial & Engineering Chemistry Research
Publication Type :
Academic Journal
Accession number :
94778237
Full Text :
https://doi.org/10.1021/ie5000505