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Dimerization of a 3-substituted oxindole at C-3 and its application to the synthesis of...

Authors :
Fang, Cheng-Lin
Horne, Stephen
Source :
Journal of the American Chemical Society. 10/19/94, Vol. 116 Issue 21, p9480. 7p. 5 Black and White Photographs, 17 Diagrams.
Publication Year :
1994

Abstract

Describes the dimerization of an oxindole on good yield at C-3 form from a benzylic quaternary carbon-carbon bond. Application of the oxindole in the synthesis of folicanthine; Proposal of a radical anion chain mechanism; Characteristics of the dimeric indole alkaloids; Determination of the molecular structure of folicanthine by X-ray crystallography.

Details

Language :
English
ISSN :
00027863
Volume :
116
Issue :
21
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
9502211636
Full Text :
https://doi.org/10.1021/ja00100a010