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Effect of macrocyclic ligand constraints upon the kinetics of complex formation and dissociation...
- Source :
-
Inorganic Chemistry . 3/29/95, Vol. 34 Issue 7, p1844. 8p. 3 Diagrams, 2 Charts. - Publication Year :
- 1995
-
Abstract
- Investigates the kinetics of copper(II) reacting with cyclohexanediyl derivatives of cyclic tetrathiaether. Macrocylic ligand constraints; Metal-ion exchange; Proposed stepwise mechanism; Intermediate interconversions; Consideration of intermediate buildup for the polythiaethers; Assignment of rate-determining step.
- Subjects :
- *CYCLOHEXANE
*ETHER (Anesthetic)
*REACTIVITY (Chemistry)
COPPER reactivity
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 34
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 9508223650
- Full Text :
- https://doi.org/10.1021/ic00111a036