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A Semi-Pinacol Rearrangement Approach to Bicyclo[3.2.1]octan-2-ones and Bicyclo[3.2.1]octan-3-ones.
- Source :
-
Synlett . 2008, Issue 14, p2155-2157. 3p. - Publication Year :
- 2008
-
Abstract
- A diastereoselective approach to bicyclo[3.2.1]octan-2-ones and -3-ones is achieved by means of the semi-pinacol rearrangement of 2,3-epoxy silyl ethers. The key 1,2-migration is stereospecific. This method is easily amenable to an enantioselective synthesis by utilizing nonracemic norcamphor and related compounds. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09365214
- Issue :
- 14
- Database :
- Academic Search Index
- Journal :
- Synlett
- Publication Type :
- Academic Journal
- Accession number :
- 95202040
- Full Text :
- https://doi.org/10.1055/s-2008-1077902