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Concurrent α-Iodination and N-Arylation of Cyclic β-Enaminones.
- Source :
-
Synlett . 2010, Issue 2, p231-234. 4p. - Publication Year :
- 2010
-
Abstract
- A variety of N-substituted 3-aminocyclohex-2-enones were converted into the corresponding N-arylated α-iodo enaminones in high yields via concurrent α-iodination and N-arylation mediated by ArI(OAc)2. A mechanism is postulated to account for the reaction differences between the cyclic and the acyclic β-enamin�ones, which undergo predominant α-acetoxylation under the same reaction conditions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *IODINATION
*ARYLATION
*CARBONYL compounds
*ENAMINES
*ACYCLIC acids
Subjects
Details
- Language :
- English
- ISSN :
- 09365214
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Synlett
- Publication Type :
- Academic Journal
- Accession number :
- 95202634
- Full Text :
- https://doi.org/10.1055/s-0029-1219164