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Experimental and DFT study on the catalytic asymmetric hydrogenation performance of (1S,2S)-DPEN-Ru(TPP)2 encapsulated in zeolite.

Authors :
Shi, Xiufeng
Fan, Binbin
Xing, Bin
Liu, Gang
Pang, Xianyong
Ren, Ruipeng
Li, Ruifeng
Source :
Journal of Molecular Catalysis A: Chemistry. Apr2014, Vol. 385, p85-90. 6p.
Publication Year :
2014

Abstract

Highlights: [•] Asymmetric chiral Ru(II) complexes were encapsulated in zeolite MY. [•] The complex encapsulated in LiY has higher ee selectivity than the homogenous. [•] The alkali metal cation exchanged Y has different host effect to the complex. [•] The reactivity was supported by DFT calculation and UV–vis spectra ananlysis. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
13811169
Volume :
385
Database :
Academic Search Index
Journal :
Journal of Molecular Catalysis A: Chemistry
Publication Type :
Academic Journal
Accession number :
95227122
Full Text :
https://doi.org/10.1016/j.molcata.2014.01.023