Syntheses and Characterization of the Coordination Compounds of N-(2-hydroxymethylphenyl)-C-(3'-carboxy-2'-hydroxyphenyl)thiazolidin-4-one.

A dry benzene solution of the Schiff base N-(2-hydroxymethylphenyl)-3'-carboxy-2'-hydroxybenzylideneimine upon reacting with mercaptoacetic acid undergoes cyclization and forms N-(2-hydroxymethylphenyl)-C-(3'-carboxy-2'-hydroxyphenyl)thiazolidin-4-one, LH3 (I). A MeOH solution of I reacts with Co(II), Ni(II), Cd(II), Zr(OH)2(IV), and UO2(VI) ions and forms the monomeric coordination compounds, [M(LH)(MeOH)3] [where M = Co(II), Ni(II)], [M' (LH)(MeOH)] [here M' = Cd(II), UO2(VI)] and [Zr(OH)2(LH)(MeOH)]. The coordination compounds have been characterized on the bases of elemental analyses, molar conductance, molecular weight, spectral (IR, NMR, and reflectance) studies, and magnetic susceptibility measurements. I behaves as a dibasic tridentate OOS donor ligand in these compounds. The compounds are nonelectrolytes (ΛM = 3.8-8.9 mho cm2 mol-1 ) in DMF. A tetrahedral structure for [Cd(LH)(MeOH)] and an octahedral structure for the remaining compounds are suggested. [ABSTRACT FROM AUTHOR]