The effect of polymer matrices on the thermal hazard properties of RDX-based PBXs by using model-free and combined kinetic analysis.

Highlights: [•] Nonisothermal decomposition kinetics of RDX and its PBXs has been investigated. [•] The kinetic models are determined by both master plot and combined kinetic analysis methods. [•] The constant rate temperature profiles and isothermal curves are predicted by obtained kinetic triplets. [•] The storage safety parameters are simulated based on thermal explosion theory. [ABSTRACT FROM AUTHOR]