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Highly efficient Cu(I)-catalyzed trifluoromethylation of aryl(heteroaryl) enol acetates with CF3 radicals derived from CF3SO2Na and TBHP at room temperature.

Authors :
Lu, Yang
Li, Yaming
Zhang, Rong
Jin, Kun
Duan, Chunying
Source :
Journal of Fluorine Chemistry. May2014, Vol. 161, p128-133. 6p.
Publication Year :
2014

Abstract

Highlights: [•] This reaction is high-yielding and wide functional group tolerance. [•] A variety of α-trifluoromethyl aryl ketones can be prepared by this practical method. [•] The reaction is experimentally simple and carried out at room temperature. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00221139
Volume :
161
Database :
Academic Search Index
Journal :
Journal of Fluorine Chemistry
Publication Type :
Academic Journal
Accession number :
95631730
Full Text :
https://doi.org/10.1016/j.jfluchem.2014.01.020