ChemInform Abstract: Chiral-Zn(NTf2)2-Complex-Catalyzed Diastereo- and Enantioselective Direct Conjugate Addition of Arylacetonitriles to Alkylidene Malonates.

Authors :: Yao, Jingjing
Liu, Xiaohua
He, Peng
Zhu, Yin
Lian, Xiangjin
Lin, Lili
Feng, Xiaoming
Source :: ChemInform. May2014, Vol. 45 Issue 19, pno-no. 1p.
Publication Year :: 2014
Abstract: Chiral N,N′-dioxide/Zn(NTf2)2 complexes are demonstrated to be highly effective in the direct asymmetric conjugate addition of arylacetonitriles to alkylidene malonates under mild conditions. [ABSTRACT FROM AUTHOR]

Subjects :: *CHIRALITY
*CHIRAL centers
*MALONATES
*LEWIS acidity
*LIGAND exchange reactions

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