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ChemInform Abstract: A Novel Dumbbell-Like Polyoxometalate Assembled of Copper(II)-Disubstituted Monovacant Keggin Polyoxoanions with a Tetranuclear Copper Cluster.
- Source :
-
ChemInform . May2014, Vol. 45 Issue 21, pno-no. 1p. - Publication Year :
- 2014
-
Abstract
- The dimeric [Cu(bipy)(μ2-OH)]4 [(H2O) (bipy)2HPW11Cu2O39] 2·2EtOH·10H2O Keggin polyoxometalate is prepared by solvothermal reaction of Cu(NO3)2, H3PW12O40, and bipy in H2O/EtOH (2:1) solution (pH 4.6 adjusted with H3PO3, autoclave, 150 °C, 3 d; 38% yield). [ABSTRACT FROM AUTHOR]
- Subjects :
- *KEGGIN anions
*COPPER clusters
*DIMERIC ions
*CHEMICAL reactions
*SOLVOLYSIS
Subjects
Details
- Language :
- English
- ISSN :
- 09317597
- Volume :
- 45
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- ChemInform
- Publication Type :
- Academic Journal
- Accession number :
- 95907516
- Full Text :
- https://doi.org/10.1002/chin.201421020