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Three-dimensional hydrogel frameworks for high-temperature proton exchange membrane fuel cells.
- Source :
-
Journal of Materials Science . Aug2014, Vol. 49 Issue 15, p5481-5491. 11p. 3 Diagrams, 1 Chart, 10 Graphs. - Publication Year :
- 2014
-
Abstract
- With an aim of enhancing anhydrous proton conductivity and phosphoric acid (H3PO4) retention, we here report the employment of three-dimensional (3D) polyacrylamide- graft-chitosan (PAAm- g-CS) frameworks as supporters to load enormous H3PO4. Intrinsic microporous structure can seal H3PO4 molecules in the interconnected 3D frameworks of PAAm- g-CS matrix during a dehydration process. The hydrogel membranes are thoroughly characterized by morphology observation, structural analysis, swelling kinetics, proton-conducting performances as well as electrochemical behaviors. Results show that H3PO4 loading and therefore proton conductivity of the resultant PEMs are dramatically improved by employing PAAm- g-CS matrix in comparison with H3PO4-doped polybenzimidazole membranes. The highest H3PO4 loading and anhydrous proton conductivity are 92.2 wt % and 0.083 S cm-1 at 165 °C, respectively. The high H3PO4 loading, reasonable proton conductivity in combination with simple preparation, low cost, and scalable matrix demonstrates the potential use of PAAm- g-CS hydrogel membranes in high-temperature proton exchange membrane fuel cells. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00222461
- Volume :
- 49
- Issue :
- 15
- Database :
- Academic Search Index
- Journal :
- Journal of Materials Science
- Publication Type :
- Academic Journal
- Accession number :
- 95993787
- Full Text :
- https://doi.org/10.1007/s10853-014-8261-9