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Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds.
- Source :
-
Chemistry - A European Journal . Jun2014, Vol. 20 Issue 23, p6866-6870. 5p. - Publication Year :
- 2014
-
Abstract
- An unprecedented silver-catalyzed formal insertion of arynes into RfI (Rf=CF3, C2F5) bonds has been developed. This protocol provides easy access to various ortho-perfluoroalkyl iodoarenes under mild conditions. In this insertion reaction, an ionic atom-transfer reaction of RfI occurs, and a silver-mediated metathesis process is involved in the efficient transfer of the electropositive iodine atom. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 20
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 96203382
- Full Text :
- https://doi.org/10.1002/chem.201402846