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Azaphosphatrane Organocatalysts in Confined Space: Cage Effect in CO2 Conversion.

Authors :
Chatelet, Bastien
Joucla, Lionel
Dutasta, Jean‐Pierre
Martinez, Alexandre
Dufaud, Véronique
Source :
Chemistry - A European Journal. Jul2014, Vol. 20 Issue 28, p8571-8574. 4p.
Publication Year :
2014

Abstract

The endohedral functionalization of a molecular cage by an azaphosphatrane unit has allowed for the creation of highly engineered catalytic cavities for efficient conversion of CO 2 into cyclic carbonates. Strong structure/activity/stability correlations have been demonstrated by careful adjustment of the size, shape, and electronic properties of the hemicryptophane host. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09476539
Volume :
20
Issue :
28
Database :
Academic Search Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
96838657
Full Text :
https://doi.org/10.1002/chem.201402058