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BiphasicSystems That Consist of Hydrophilic IonicLiquid, Water, and Ethyl Acetate: The Effects of Interactions on thePhase Behavior.
- Source :
-
Industrial & Engineering Chemistry Research . Jul2014, Vol. 53 Issue 26, p10784-10790. 7p. - Publication Year :
- 2014
-
Abstract
- Thedesign of a biphasic system is important for the developmentof liquid–liquid extraction and biphasic catalysis. In thiswork, we report a series of ternary biphasic systems that consistof hydrophilic ionic liquid (IL), water, and ethyl acetate. The effectsof the structure of the ILs (cation, anion, and substituent group),IL/water ratio, and temperature on the phase equilibrium of thesebiphasic systems were investigated. The mutual solubility was lowerin the IL/water–ethyl acetate biphasic system than in the water–ethylacetate system when ILs with strong hydration ability were introduced,such as [EMIm]OAc, [EMIm]Cl, [EMIm]NO3, [EMIm]EtSO4, and [HOEMIm]Cl. In addition, the hydrogen-bonding basicityof the IL-containing phase could be tuned by changing the IL structureor IL/water ratio. These novel IL/water-ethyl acetate biphasic systemsmay present another option in addition to hydrophobic IL–waterand aqueous biphasic systems for liquid–liquid extraction. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 08885885
- Volume :
- 53
- Issue :
- 26
- Database :
- Academic Search Index
- Journal :
- Industrial & Engineering Chemistry Research
- Publication Type :
- Academic Journal
- Accession number :
- 97011273
- Full Text :
- https://doi.org/10.1021/ie5007273