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Preparation of new Wittig reagents and their application to the synthesis of alpha, beta...

Authors :
Xu, Yibo
Flavin, Michael T.
Source :
Journal of Organic Chemistry. 11/1/96, Vol. 61 Issue 22, p7697. 5p. 4 Diagrams, 1 Chart.
Publication Year :
1996

Abstract

Presents the synthesis of the Wittig reagent [(diethoxyphosphinyl)methylidene]triphenylphosphorane using its phosphonium triflate salt. Treatment of the reagent with various aldehydes and an activated ketone; Formation of cis and trans isomers; Hydrogenation of alpha, beta-unsaturated esters.

Details

Language :
English
ISSN :
00223263
Volume :
61
Issue :
22
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
9704173816
Full Text :
https://doi.org/10.1021/jo9608275