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Theoretical insights regarding the cycloaddition behavior of push-pull stabilized carbonyl ylides.

Authors :
Weingarten, M. David
Prein, Michael
Source :
Journal of Organic Chemistry. 04/04/97, Vol. 62 Issue 7, p2001. 10p. 9 Diagrams, 3 Charts.
Publication Year :
1997

Abstract

Presents theoretical insights regarding the cycloaddition behavior of push-pull stabilized carbonyl ylides. Establishment of the stereochemistry of the cycloadduct; Application of an X-ray crystallographic study; Indications that a severe cross-ring diaxial interaction promotes a twist-boat conformation.

Details

Language :
English
ISSN :
00223263
Volume :
62
Issue :
7
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
9711154415
Full Text :
https://doi.org/10.1021/jo962184z