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Iron-Catalyzed, Chelation-Induced Remote C–HAllylation of Quinolines via 8-Amido Assistance.
- Source :
-
Organic Letters . Jul2014, Vol. 16 Issue 14, p3716-3719. 4p. - Publication Year :
- 2014
-
Abstract
- Aniron-catalyzed, 8-amido-enabled regiodivergent C–H allylationof quinolines is described. This reaction represents a rare exampleof chelation-induced geometrically inaccessible C–H functionalization,allowing for the highly regio- and stereoselective preparation ofeither the C5- or the C4-allylated quinoline scaffolds regiocontrolledby the catalytic systems. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 16
- Issue :
- 14
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 97112184
- Full Text :
- https://doi.org/10.1021/ol501534z