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Regioselective 1,4-conjugate hydrocyanation of dienones using potassium hexacyanoferrate(II) as an eco-friendly cyanide source.

Authors :
Zheng Li
Junjun Yin
Tianpeng Li
Gong Wen
Xiaoli Shen
Jingya Yang
Source :
Tetrahedron. Sep2014, Vol. 70 Issue 35, p5619-5625. 7p.
Publication Year :
2014

Abstract

A highly regioselective 1,4-conjugate hydrocyanation of dienones using potassium hexacyanoferrate(II) as an original eco-friendly cyanide source, benzoyl chloride as a promoter and potassium carbonate as a catalyst is described. This protocol has advantages of non-toxic cyanating agent, high regioselectivity, high yield, and simple work-up procedure. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00404020
Volume :
70
Issue :
35
Database :
Academic Search Index
Journal :
Tetrahedron
Publication Type :
Academic Journal
Accession number :
97186461
Full Text :
https://doi.org/10.1016/j.tet.2014.06.079