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Stereoselective Total Syntheses of Paecilomycins E and F through a Protecting Group Directed Diastereoselective Intermolecular Nozaki-Hiyama-Kishi (NHK) Reaction.
- Source :
-
European Journal of Organic Chemistry . Aug2014, Vol. 2014 Issue 23, p5023-5032. 10p. - Publication Year :
- 2014
-
Abstract
- An efficient and concise approach to the total syntheses of paecilomycins E ( 1) and F ( 2) is described. A protecting group directed intermolecular diastereoselective Nozaki-Hiyama-Kishi (NHK) reaction, a Julia-Kocienski olefination, a Sharpless asymmetric dihydroxylation, and De Brabander's lactonization protocol are used as the key steps. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 2014
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 97351395
- Full Text :
- https://doi.org/10.1002/ejoc.201402133