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Enhancing photoluminescence with Li-doped CaTiO3:Eu3+ red phosphors prepared by solid state synthesis.
- Source :
-
Journal of Luminescence . Nov2014, Vol. 155, p269-274. 6p. - Publication Year :
- 2014
-
Abstract
- Red phosphors of Li-doped CaTiO3:Eu3+ that enhance photoluminescence have been synthesized by a solid-state method, and their structure and morphology were confirmed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The luminescence property was measured using photoluminescence excitation (PLE) and photoluminescence (PL) spectra, respectively. The effect of sintered temperature and Eu3+ and Li+ concentration in as-prepared series phosphors was studied. Results indicate that the optimal luminescence properties of CaTiO3:Eu3+ (CTE) phosphors are typically obtained at 1300 °C with 12 mol% of Eu3+ concentration, and the emission intensity can be greatly enhanced by the incorporation of Li+ into the CTE phosphors, attributing that Li not only compensates positive charge defect by replacement of Ca2+ with Eu3+, but also plays a role of flux, which could enhance the crystallinity of the phosphors. The intensity of the optimal Li-doped CaTiO3:Eu3+ phosphor (CLTE) is 2.3 times of that of CTE. PL spectrum showed that CLTE phosphor was efficiently excited by near-ultraviolet light at wavelength around 398 nm and emitted intensive red light with a peak around 616 nm corresponding to the 5D0→7F2 transition of Eu3+. Furthermore, this phosphor has very good thermal stability and high color purity, implying the potential to be a promising red phosphor in white light emitting diodes. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00222313
- Volume :
- 155
- Database :
- Academic Search Index
- Journal :
- Journal of Luminescence
- Publication Type :
- Academic Journal
- Accession number :
- 97437803
- Full Text :
- https://doi.org/10.1016/j.jlumin.2014.06.051