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Conductometric study of complex formation between benzylbisthiosemicarbazone and metal cations in acetonitrile, dimethylformamide, and their binary mixtures.
- Source :
-
Russian Journal of General Chemistry . Jul2014, Vol. 84 Issue 7, p1429-1433. 5p. - Publication Year :
- 2014
-
Abstract
- We report on conductometric study of complexation between benzylbisthiosemicarbazone [(2 E,2′ E)-2,2′-(1,2-diphenylethane-1,2-diylidene)bis(hydrazine-1-carbothioamide)] with Zn, Cr, Co, and Ni cations at different temperatures in acetonitrile-dimethylformamide binary solvents of varied composition. The equilibrium constant and standard thermodynamic parameters (Δ H and Δ S) of the complexes formation have been determined and found to be dependent on the binary solvent composition, the metal ion nature, and temperature. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 84
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 97502206
- Full Text :
- https://doi.org/10.1134/S1070363214070317