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Transition Metal-Free ipso-Functionalization of Arylboronic Acids and Derivatives.
- Source :
-
Advanced Synthesis & Catalysis . Aug2014, Vol. 356 Issue 11/12, p2395-2410. 16p. - Publication Year :
- 2014
-
Abstract
- Arylboronic acids and their derivatives have been widely exploited as important synthetic precursors in organic synthesis, materials science, and pharmaceutical development. In addition to numerous applications in transition metal-mediated cross-coupling reactions, transition metal-free transformations involving arylboronic acids and derivatives have recently received a surge of attention for converting the CB bond to CC, CN, CO, and many other CX bonds. Consequently, a wide range of useful compounds, e.g., phenols, anilines, nitroarenes, and haloarenes, has been readily synthesized. Amongst these efforts, many versatile reagents have been developed and a lot of practical approaches demonstrated. The research in this promising field is summarized in the current review and organized on the basis of the type of bonds being formed. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 356
- Issue :
- 11/12
- Database :
- Academic Search Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 97503406
- Full Text :
- https://doi.org/10.1002/adsc.201400305