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Structural Interconversion of Bimetallic Carbonyl Clusters Induced by a NHC Ligand and Its Selectivity on Fragments.
- Source :
-
Zeitschrift für Anorganische und Allgemeine Chemie . Aug2014, Vol. 640 Issue 10, p1983-1986. 4p. - Publication Year :
- 2014
-
Abstract
- The reactions of IMes-HCl with bimetallic iron-copper clusters were investigated and it showed that interconversions among bimetallic Fe xCu y(CO) zn- clusters were induced by IMes-HCl. The reaction priority of IMes-HCl with fragments in Fe xCu y(CO) zn- was also investigated and the reaction behaviors of zero valent Fe(CO)4 and divalent Fe(CO)4 with IMes-HCl were discussed. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00442313
- Volume :
- 640
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Zeitschrift für Anorganische und Allgemeine Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 97581370
- Full Text :
- https://doi.org/10.1002/zaac.201400108