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Adsorption–degradation synergetic effects on removal of methylene blue over heterostructured TiO2/Co4S4.23Se3.77 composites.
- Source :
-
Journal of Molecular Catalysis A: Chemistry . Nov2014, Vol. 394, p121-128. 8p. - Publication Year :
- 2014
-
Abstract
- Novel heterostructured TiO 2 /Co 4 S 4.23 Se 3.77 composites were synthesized by a combination of solid-state and sol–gel methods, and were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, UV–vis diffuse reflectance spectroscopy, and photocurrent measurements. The results of photocatalytic degradation of methylene blue over the as-prepared materials indicate that photocatalytic efficiency is closely related to the composition of the materials, and the 30%TiO 2 /Co 4 S 4.23 Se 3.77 catalyst exhibits the best adsorption and photodegradation efficiency under sunlight or visible-light irradiation. The adsorption capacity of 30%TiO 2 /Co 4 S 4.23 Se 3.77 for methylene blue is 18.59 mg/g calculated based on the Langmuir adsorption model. Adsorption kinetics studies show that the process fits well with a pseudo-second-order rate mechanism. Recycle experiments confirm that the 30%TiO 2 /Co 4 S 4.23 Se 3.77 catalyst is stable. The present work illustrates a new way for the design and syntheses of stable and high-efficiency catalysts applicable for the degradation of organic pollutants. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13811169
- Volume :
- 394
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Catalysis A: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 97842596
- Full Text :
- https://doi.org/10.1016/j.molcata.2014.07.012