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Cobalt-Catalyzed, Aminoquinoline-Directed C(sp2)H Bond Alkenylation by Alkynes.
- Source :
-
Angewandte Chemie . Sep2014, Vol. 126 Issue 38, p10373-10376. 4p. - Publication Year :
- 2014
-
Abstract
- A method for cobalt-catalyzed, aminoquinoline- and picolinamide-directed C(sp2)H bond alkenylation by alkynes was developed. The method shows excellent functional-group tolerance and both internal and terminal alkynes are competent substrates for the coupling. The reaction employs a Co(OAc)2⋅4 H2O catalyst, Mn(OAc)2 co-catalyst, and oxygen (from air) as a terminal oxidant. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 126
- Issue :
- 38
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 97983910
- Full Text :
- https://doi.org/10.1002/ange.201404579