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Influence of copper concentration in solutions on the growth mechanism and performance of electrodeposited Cu(In,Al)Se2 solar cells.
- Source :
-
Solar Energy Materials & Solar Cells . Sep2014, Vol. 128, p27-35. 9p. - Publication Year :
- 2014
-
Abstract
- We conducted a chronoamperometric study to observe the electrochemical behaviors of the nucleation mechanism of electrodeposited Cu(In,Al)Se 2 films. A change from instantaneous nucleation to progressive nucleation was observed by increasing the copper concentration. SEM and EDS analyses demonstrated that the surface morphologies and chemical compositions of precursor and post-annealed Cu(In,Al)Se 2 films were influenced by the nucleation mechanism. They exhibited that Cu(In,Al)Se 2 films had roughly cauliflower-like and triangular structures with Cu-poor composition at the instantaneous nucleation mechanism, whereas smooth and round structures with Cu-rich composition at the progressive nucleation mechanism. Additionally, the quality, growth orientation, composition phase, and optical energy band gap of Cu(In,Al)Se 2 films were examined using X-ray diffraction (XRD) patterns, Raman spectra, and ( αhν ) 2 vs. hν plots (UV–vis). Thereafter, the performances of rudimentary Cu(In,Al)Se 2 solar cells fabricated at various copper concentrations were discussed, the conversion efficiency of electrodeposited Cu(In,Al)Se 2 solar cells were unpublished in previous literatures. Our studies demonstrated that the performances of Cu(In,Al)Se 2 solar cells were significantly related to the surface morphology and composition of Cu(In,Al)Se 2 absorber layer. The highest conversion efficiency of Cu(In,Al)Se 2 solar cells fabricated at a 2-mM copper concentration was 1.96% with open-circuit voltage, short-circuit current, fill factor, R sh and R s values of 0.189 V, 29.21 mA/cm 2 , 35.4%, 125 Ω and 2.82 Ω, respectively. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09270248
- Volume :
- 128
- Database :
- Academic Search Index
- Journal :
- Solar Energy Materials & Solar Cells
- Publication Type :
- Academic Journal
- Accession number :
- 98736203
- Full Text :
- https://doi.org/10.1016/j.solmat.2014.05.007