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Reactions of 1,3-dehydroadamantane with inorganic oxygen-free acids.
- Source :
-
Russian Journal of Organic Chemistry . Sep2014, Vol. 50 Issue 9, p1276-1278. 3p. - Publication Year :
- 2014
-
Abstract
- A convenient and efficient procedure has been developed for the synthesis of 1-azidoadamantane, 1-adamantyl isocyanate, and 1-adamantyl isothiocyanate by reaction of 1,3-dehydroadamantane with hydrazoic, isocyanic, and isothiocyanic acids, respectively, under mild conditions. The reaction of 1,3-dehydroadamantane with hydrogen cyanide under analogous conditions gives adamantane-1-carbonitrile in a poor yield which may be improved using hexane as solvent. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10704280
- Volume :
- 50
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Russian Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 98837201
- Full Text :
- https://doi.org/10.1134/S1070428014090073