Back to Search
Start Over
Palladacycle Catalyzed Asymmetric PH Addition of Diarylphosphines to N-Enoyl Phthalimides.
- Source :
-
Chemistry - A European Journal . Oct2014, Vol. 20 Issue 44, p14514-14517. 4p. - Publication Year :
- 2014
-
Abstract
- The first asymmetric phospha-Michael addition of diarylphosphines to N-enoyl phthalimides has been developed in the presence of a chiral palladacycle catalyst. A library of free chiral tertiary phosphine adducts were directly obtained with excellent yields and enantioselectivities. Products can be subsequently functionalized to afford β-phosphinoamides, the direct preparation of which from cinnamides has been notoriously challenging. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PALLADACYCLES
*PHTHALIMIDES
*ENANTIOSELECTIVE catalysis
*CHIRALITY
*PHOSPHINE
Subjects
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 20
- Issue :
- 44
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 98982193
- Full Text :
- https://doi.org/10.1002/chem.201403885