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Origin and Location of Electrons and Protons during the Formation of Intermetalloid Clusters [Sm@Ga3− xH3−2 xBi10+ x]3− ( x=0, 1).
- Source :
-
Angewandte Chemie International Edition . Oct2014, Vol. 53 Issue 44, p11979-11983. 5p. - Publication Year :
- 2014
-
Abstract
- Reaction of [GaBi3]2− with [Sm(C5Me4H)3] yielded the first protonated ternary intermetalloid clusters [Sm@Ga3− xH3−2 xBi10+ x]3− ( 1; x=0,1). The presence of the GaH bonds and the transfer of electrons and protons during the formation of 1 were elucidated by a combination of experimental and quantum chemical methods, thereby rationalizing the role of the solvent ethane-1,2-diamine as a Brønsted acid. As an organic by-product, we observed the previously unknown octamethylfulvene ( 2) upon CC coupling of (C5Me4H)−. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ELECTRONS
*PROTONS
*QUANTUM chemistry
*CHEMICAL bonds
*PHOTON-electron interactions
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 53
- Issue :
- 44
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 98999309
- Full Text :
- https://doi.org/10.1002/anie.201407288