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Evolution of Co charge disproportionation with Na order in NaxCoO2.
- Source :
-
Physical Review B: Condensed Matter & Materials Physics . Sep2014, Vol. 90 Issue 11, p115151-1-115151-11. 11p. - Publication Year :
- 2014
-
Abstract
- 59Co NMR experiments have been performed on single crystals of the layered cobaltate NaxCoO2 with x = 0.77, which is an antiferromagnet with Néel temperature TN = 22 K. In this metallic phase, six Co sites are resolved in the NMR spectra, with distinct quadrupole frequencies ʋQ, magnetic shifts KZZ and nuclear spin lattice relaxation rates 1/7). Contrary to the x = 1/2 or x = 2/3 phases, the 3D stacking of the Na planes is not perfect for x = 0.77 but this does not influence markedly the electronic properties. We evidence that the magnetic and charge properties of the Co sites are highly correlated with each other as KZZ and (1/T1)1/2 scale linearly with ʋQ . The data analysis allows us to separate the contribution ʋlattQ of the ionic charges to ʋQ from that ʋelQ due to the hole orbitals on the Co sites. We could extend coherently this analysis to all the known phases in the Na cobaltate phase diagram. The variation with x of ʋlattQ is found to fit rather well numerical computations done in a point charge model. The second term ʋelQ allowed us to deduce the hole concentration on the cobalts. These detailed experimental results should stimulate theoretical calculations of the electronic structure involving both the Co orbital configurations and DMFT approaches to take into account the electronic correlations. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10980121
- Volume :
- 90
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Physical Review B: Condensed Matter & Materials Physics
- Publication Type :
- Academic Journal
- Accession number :
- 99260893
- Full Text :
- https://doi.org/10.1103/PhysRevB.90.115151