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Amide-based diarylmaleimide derivatives and polymers: Highly selective and ratiometric fluorescence sensing for anions.
- Source :
-
Dyes & Pigments . Feb2015, Vol. 113, p129-137. 9p. - Publication Year :
- 2015
-
Abstract
- A series of diarylmaleimide derivatives and polymers based on amide group were designed and synthesized to detect anions selectively and sensitively. Three bisindolylmaleimide derivatives (FAM-p, FAM-m and FAM-o) employing trifluoroacetamide as receptor exhibited strong fluorescent quenching upon fluoride and cyanide. Trifluoroacetamide receptor was replaced by acetamide to obtain other two derivatives (AM-p and AM-o) which showed higher selectivity than FAMs with sensing for only fluoride. The diarylmaleimide derivatives were introduced into the backbone of polyfluorene by Suzuki reaction to prepare polymer PFAM and PAM with same sensing selectivity for anions as FAM and AM, respectively. PFAM and PAM were found to be ratiometric fluorescence sensors for a fluorescence resonance energy transfer (FRET) from fluorene segments to diphenylmaleimide units. The experimental and DFT/TDDFT calculation results demonstrated that the interaction mechanism of FAMs with F − and CN − was hydrogen bond interaction and nucleophilic addition reaction, respectively. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01437208
- Volume :
- 113
- Database :
- Academic Search Index
- Journal :
- Dyes & Pigments
- Publication Type :
- Academic Journal
- Accession number :
- 99636628
- Full Text :
- https://doi.org/10.1016/j.dyepig.2014.08.006