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A Nanosized {Ag@Ag12} "Molecular Windmill" Templated by Polyoxometalates Anions.
- Source :
-
Inorganic Chemistry . 11/3/2014, Vol. 53 Issue 21, p11584-11588. 5p. - Publication Year :
- 2014
-
Abstract
- Reaction of multidentate 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (L) ligand with Ag(I) ions in the existence of H3PW12O40 as anionic template under hydrothermal conditions results in tridecanuclear silver cluster-polyoxometalates hybrid: {Ag13L12}{PW12O40}4·30H2O (1). X-ray single crystal diffraction analysis indicates that the main structural feature of 1 is a nanosized molecular windmill-shaped polynuclear Ag cluster with intriguing {M@M12}-type cuboctahedral topology. The as-synthesized compound exhibits effective photocatalytic activity in the photodegradation of Rhodamine-B (RhB) and antibacterial activity against Escherichia coli, respectively. [ABSTRACT FROM AUTHOR]
- Subjects :
- *POLYOXOMETALATES
*SILVER ions
*ANIONS
*NANOPARTICLES
*CHEMICAL templates
*WINDMILLS
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 53
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 99642174
- Full Text :
- https://doi.org/10.1021/ic501657p