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Coordination mode of pentadentate ligand derivative of 5-amino-1,3,4-thiadiazole-2-thiol with nickel(II) and copper(II) metal ions: Synthesis, spectroscopic characterization, molecular modeling and fungicidal study.
- Source :
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Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy . Feb2015 Part B, Vol. 136, p672-681. 10p. - Publication Year :
- 2015
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Abstract
- Complexes of nickel(II), and copper(II) were synthesized with pantadentate ligand i.e. 3,3′-thiodipropionicacid-bis(5-amino-1,3,4-thiadiazole-2-thiol) (L). The ligand was synthesized by the condensation of thiodipropionic acid and 5-amino-1,3,4-thiadiazole-2-thiol in 1:2 ratio, respectively. Synthesized ligand was characterized by elemental analysis, mass, 1 H NMR, IR, and molecular modeling. All the complexes were characterized by elemental analysis, molar conductance, magnetic moment, IR, electronic spectra, ESR, and molecular modeling. The newly synthesized complexes possessed general composition [M(L)X 2 ] where M = Ni(II), Cu(II), L = pantadentate ligand and X = Cl − , CH 3 COO − . The IR spectral data indicated that the ligand behaved as a pantadentate ligand and coordinated to the metal ion through N 2 S 3 donor atoms. The molar conductance value of Ni(II), and Cu(II) complexes in DMSO corresponded to their electrolytic behavior. On the basis of spectral study, octahedral and tetragonal geometry was assigned for Ni(II) and Cu(II) complexes, respectively. In vitro fungicidal study of ligand and its complexes was investigated against fungi Candida albicans , Candida parapsilosis , Candidia krusei , and Candida tropicalis by means of well diffusion method. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13861425
- Volume :
- 136
- Database :
- Academic Search Index
- Journal :
- Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy
- Publication Type :
- Academic Journal
- Accession number :
- 99699661
- Full Text :
- https://doi.org/10.1016/j.saa.2014.09.081