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The first manganese N-confused porphyrins catalyzed oxidation of alkene.
- Source :
-
Journal of Molecular Catalysis A: Chemistry . Dec2014, Vol. 395, p180-185. 6p. - Publication Year :
- 2014
-
Abstract
- A series of N -methyl N-confused porphyrin manganese complexes ( 3a – 3f ) were synthesized and characterized by UV–vis, XPS, HR-MS and cyclic voltammetry. These complexes were utilized to catalyze the styrene oxidation. It turned out their catalytic activities were comparable with manganese tetraphenylporphyrin (MnTPP). Among all investigated manganese N-confused porphyrins, the most electron deficient 3f exhibited the best catalytic activity for the alkene oxidation. The proposed mechanism for the catalytic oxidation has also been described. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13811169
- Volume :
- 395
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Catalysis A: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 99736215
- Full Text :
- https://doi.org/10.1016/j.molcata.2014.08.016