In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions.

Authors :: Yuan-Zhu Zhang
Song Gao
Osamu Sato
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 2015, Vol. 44 Issue 2, p480-483. 4p.
Publication Year :: 2015
Abstract: An azido-bridged chair-like decanuclear cluster: [CoII10(bzp)8(Metz)2(N3)18]·4MeOH·3H2O (1, bzp = 2-benzoylpyridine and HMetz = 5-methyl-1H-tetrazole) was prepared with in situ tetrazolate anions as templates in a sealed system. 1 containing both octahedral and tetrahedral Co(ii) ions exhibited slow relaxation of magnetization with an effective barrier of 26 K under an applied dc field of 1 kOe. [ABSTRACT FROM AUTHOR]

Subjects :: *COBALT
*AZIDO group
*TETRAZOLES
*CHEMICAL templates
*METAL ions
*MOLECULAR clusters
*MAGNETIZATION
*CHEMICAL relaxation

Language :: English
ISSN :: 14779226
Volume :: 44
Issue :: 2
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 99940965
Full Text :: https://doi.org/10.1039/c4dt03211j

Full Text Access

Tools