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Poly[[[tri(urea-kappaO)manganese(II)]-mu-thiocyanato-kappa2N:S-mercury(II)]-tri-mu-tetrathiocyanato].

Authors :
Wang XQ
Yu WT
Xu D
Lu MK
Yuan DR
Source :
Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2002 Jan; Vol. 58 (Pt 1), pp. m36-8. Date of Electronic Publication: 2001 Dec 14.
Publication Year :
2002

Abstract

The title complex, [MnHg(SCN)4(CH4N2O)3]n, consists of slightly distorted octahedral MnN3O3 and tetrahedral HgS4 units. The Mn(II) atom is coordinated by the O atoms of three urea molecules and by the N atoms of three SCN- ions; Hg(II) is coordinated by four S atoms from SCN- ions. Each pair of Mn(II) and Hg(II) atoms is connected by an -SCN- bridge, forming infinite two-dimensional -Mn-NCS-Hg- networks.

Details

Language :
English
ISSN :
0108-2701
Volume :
58
Issue :
Pt 1
Database :
MEDLINE
Journal :
Acta crystallographica. Section C, Crystal structure communications
Publication Type :
Academic Journal
Accession number :
11781466
Full Text :
https://doi.org/10.1107/s010827010101719x