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Reaction of singlet oxygen with Ir(I) and Rh(I) thiolato complexes: oxidative addition vs. S-oxidation.

Authors :
Ho DG
Ismail R
Franco N
Gao R
Leverich EP
Tsyba I
Ho NN
Bau R
Selke M
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2002 Mar 21 (6), pp. 570-1.
Publication Year :
2002

Abstract

Singlet oxygen reacts with Ir(I) and Rh(I) thiolato complexes to form the corresponding Ir(III) and Rh(III) peroxo thiolato complexes which do not undergo intramolecular oxidation of the thiolate moiety.

Details

Language :
English
ISSN :
1359-7345
Issue :
6
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
12120127
Full Text :
https://doi.org/10.1039/b110396m