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Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2002 Mar 07 (5), pp. 480-1. - Publication Year :
- 2002
-
Abstract
- Novel monodentate phosphorus ligands containing the 1,1'-spirobiindane backbone have been synthesized and applied in the asymmetric rhodium-catalyzed hydrogenation of functionalized olefins, providing excellent enantioselectivities (up to 99.3% ee).
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 5
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 12120551
- Full Text :
- https://doi.org/10.1039/b109827f