A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions.

Authors :: Tao J
Zhang Y
Tong ML
Chen XM
Yuen T
Lin CL
Huang X
Li J
Source :: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2002 Jul 07 (13), pp. 1342-3.
Publication Year :: 2002
Abstract: A novel coordination polymer of mixed-valence copper(I,II) with 4,4'-bipyridine and in situ oxidized isophthalate, [Cu2(ipO)(4,4'-bpy)] (ipOH = 2-hydroxyisophthalate), was hydrothermally synthesized and crystallographically characterized to be a laminated structure via weak copper(II)--oxygen interactions.

Subjects :: 2,2'-Dipyridyl chemistry
Copper chemistry
Crystallography, X-Ray
Hot Temperature
Ligands
Magnetics
Models, Chemical
Molecular Structure
Oxidation-Reduction
Phthalic Acids chemistry
Copper metabolism
Oxygen metabolism
Polymers chemistry

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