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Diverging stereochemical pathways in an intramolecular Diels-Alder reaction determined by dienophile structure.
- Source :
-
Organic letters [Org Lett] 2003 Aug 07; Vol. 5 (16), pp. 2777-80. - Publication Year :
- 2003
-
Abstract
- [reaction: see text] Intramolecular Diels-Alder cycloaddition of tolylsulfonyl alkynone 5a and vinyl ketone 19 led to single isomers with opposite diastereoselectivity. Decalin 20 incorporates the correct C(9)-C(11) stereochemical array for a projected synthesis of HMP-Y1 (1).
- Subjects :
- Stereoisomerism
Molecular Structure
Subjects
Details
- Language :
- English
- ISSN :
- 1523-7060
- Volume :
- 5
- Issue :
- 16
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 12889872
- Full Text :
- https://doi.org/10.1021/ol034823f