Back to Search
Start Over
Homochiral Zn and Cd coordination polymers containing amino acid-tetrazole ligands.
- Source :
-
Inorganic chemistry [Inorg Chem] 2003 Dec 01; Vol. 42 (24), pp. 7710-2. - Publication Year :
- 2003
-
Abstract
- The reactions of (S)-3-cyanophenylalanine with NaN(3) in the presence of H(2)O and Lewis acids (ZnCl(2) and CdCl(2)) afford two unprecedented 3D homochiral networks, mono[(S)-5-(3-tetrazoyl)-phenylalaninato]zinc(II) (1) and mono[(S)-5-(3-tetrazoyl)-phenylalaninato]cadmium(II) monoaqua(II) (2), respectively. The two compounds are isostructural with noninterpenetrated SrAl(2) topology. The structure of these coordination polymers gives new insight into Sharpless' reaction of chiral 5-substituted 1H-tetrazole and homochiral supramolecular array constructions.
Details
- Language :
- English
- ISSN :
- 0020-1669
- Volume :
- 42
- Issue :
- 24
- Database :
- MEDLINE
- Journal :
- Inorganic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 14632480
- Full Text :
- https://doi.org/10.1021/ic034685q