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Cooperative C-F...Si interaction in optically active helical polysilanes.

Authors :
Kim SY
Saxena A
Kwak G
Fujiki M
Kawakami Y
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2004 Mar 07 (5), pp. 538-9. Date of Electronic Publication: 2004 Jan 27.
Publication Year :
2004

Abstract

Cooperative amplification of the C-F...Si weak interaction between side chains and the main chain was found to afford rigid rodlike helical polysilanes with a preferential screw sense.

Details

Language :
English
ISSN :
1359-7345
Issue :
5
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
14973596
Full Text :
https://doi.org/10.1039/b314723a