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New Pb-Pb bonds: syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2004 Oct 07 (19), pp. 2224-5. Date of Electronic Publication: 2004 Aug 20. - Publication Year :
- 2004
-
Abstract
- Reaction of lead(II) chloride with biphenylmagnesium bromide yields Bp(3)Pb-PbBp(3) and [(THF)(3)Mg(mu-Cl)(3)Mg(THF)(3)][Pb(PbBp(3))(3)](Bp = biphenyl), which, upon single crystal X-ray crystallographic analysis, reveals an interesting variation of Pb-Pb bond distances.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 19
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 15467883
- Full Text :
- https://doi.org/10.1039/b408860n