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Spectrophotometric, EPR and kinetic characterisation of the >N-O* radical from 1-hydroxybenzotriazole, a key reactive species in mediated enzymatic oxidations.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2004 Oct 21 (20), pp. 2356-7. Date of Electronic Publication: 2004 Sep 07. - Publication Year :
- 2004
-
Abstract
- Characterisation of the aminoxyl (>N-O*) radical BTNO, generated from 1-hydroxybenzotriazole (HBT) by the one-electron oxidant CAN (a Ce(IV) salt), confirms BTNO as the reactive intermediate in oxidations run with the laccase/HBT system.
Details
- Language :
- English
- ISSN :
- 1359-7345
- Issue :
- 20
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 15490018
- Full Text :
- https://doi.org/10.1039/b407835g