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Easy hydrolysis of white phosphorus coordinated to ruthenium.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2005 Jul 07 (13), pp. 2234-6. Date of Electronic Publication: 2005 May 31. - Publication Year :
- 2005
-
Abstract
- The P4 molecule bound to ruthenium as an eta1-ligand in [CpRu(PPh3)2(eta1-P4)]Y (Y = PF6, CF3SO3) undergoes an easy reaction with water in exceedingly mild conditions to yield PH3, which remains coordinated to the [CpRu(PPh3)2] fragment, and oxygenated derivatives.
Details
- Language :
- English
- ISSN :
- 1477-9226
- Issue :
- 13
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 15962041
- Full Text :
- https://doi.org/10.1039/b504795a